05: Antman

Punch (X) . Turn miniature (can access small person chutes) (B) . Jump (A)
His animations would be similar to Bruce Banner's as he is a scientist.

04: Daredevil

Punch (X). Attack with nunchuk/baton thingy-ma-whatzit (B) . Jump (A).
He would be quite alert, and this would show in his animations. i.e having his head darting back and forth.
Idle animation 1 - Drop baton stick, and feel around on the ground to find it.
Idle animation 2 - Look startled and scan environment.